Blog
Blog

A Brief Discussion of the Various Causes of Material Aging in O-Ring Seals


A Brief Discussion of the Various Causes of Material Aging in O-Ring Seals
 
O-ring seal They are widely used for sealing in various types of mechanical equipment, providing effective sealing under specified temperature and pressure conditions and in diverse liquid and gaseous media, whether stationary or in motion, while also exhibiting excellent resistance to both high and low temperatures. Mingzhen Seals advises that when using rubber seals, it is essential to maintain an appropriate temperature range, ensure good sealing elasticity, and take advantage of their outstanding properties, such as ozone resistance and weather‑aging resistance. Furthermore, silicone rubber seals possess a host of superior characteristics, including being odorless, waterproof, flame‑retardant, heat‑resistant, and resistant to abrasion and oil. They can be used to manufacture thermal insulation and electrical insulating products, as well as medical‑grade silicone items, making them environmentally compliant sealing components. So, what are the primary causes of aging in O‑ring rubber seals?
 
I. Photodegradation Mechanism The primary factor responsible for the degradation of rubber sealing‑ring materials is high‑energy ultraviolet (UV) radiation, as UV wavelengths are shorter and more energetic. In addition to directly inducing chain scission and crosslinking in rubber molecules, UV exposure generates free radicals through photon absorption, which initiate and accelerate oxidative chain reactions. Furthermore, UV radiation can also exert a heating effect. Another distinctive feature of photochemical action—distinct from thermal effects—is that it predominantly occurs at the rubber surface. For specimens with high rubber content, network‑like cracks may appear on both sides, a phenomenon known as “photo‑induced surface cracking.”
 
II. Oxidation Mechanism Oxygen in O-ring elastomer materials reacts with rubber molecules via a free-radical chain‑transfer process, leading to scission of the polymer chains or excessive crosslinking and thereby altering the performance of silicone rubber products. Oxidation is one of the primary causes of aging in rubber seals.
 
III. The Effects of Ozone Ozone has a much higher chemical oxygen content and is more destructive; it likewise causes the molecular chains to break. However, the manner in which ozone affects O-ring materials varies depending on whether the rubber is subjected to deformation.
4. Effects of High Temperature: Raising the temperature can induce thermal depolymerization or thermal crosslinking in silicone O-ring seals; however, the fundamental role of heat remains unchanged. It enhances oxygen diffusion and oxidation reactions, thereby accelerating the rate of rubber oxidation—a widespread aging phenomenon known as thermo-oxidative aging.
 
V. The Role of Moisture The effects of moisture manifest in two ways: first, when silicone rubber products are exposed to humid air, rain, or immersion in water, they become prone to degradation, as water‑soluble substances and hydrophilic groups within the rubber are leached out and dissolved. Second, moisture can induce hydrolysis or absorption, which—particularly under alternating conditions of water immersion and atmospheric exposure—accelerates the deterioration of the rubber sealing material.
 
6. Mechanical Stress Under repeated mechanical stress, the molecular chains of rubber seals can break, generating free radicals and triggering oxidative chain reactions, thereby initiating a mechanochemical process. This involves both mechanical scission of the polymer chains and mechanical oxidation. Furthermore, under stress, ozone cracking is readily induced. 7. Other Factors In addition to the above, chemical media (such as hydraulic fluids), redox‑active metal ions, high‑energy radiation, electrical effects, and biological factors can also influence the degree of aging of O‑ring sealing materials.

Related News


What is the difference between silicone stoppers and rubber stoppers?

Which is better—silicone plugs or rubber plugs? Today, let’s explore their differences and where each excels. First, rubber plugs are a common type of industrial accessory, offering significant advantages such as dustproofing, waterproofing, wear resistance, tear resistance, aging resistance, oil resistance, and protection against ozone exposure. Rubber materials come in various types, and different formulations can be created by combining dozens of chemical ingredients. This allows for tailored properties to meet diverse application needs. For industries requiring tight seals—such as machinery, electronics, transportation, construction, and even aerospace and defense—rubber plugs are often the most suitable choice. Silicone plugs share some similarities with rubber plugs: both can be molded and vulcanized using molds in silicone product manufacturing facilities. However, silicone stands out for being more environmentally friendly, offering superior resistance to high and low temperatures, and providing a smoother, more pleasant tactile experience. It can safely remain in prolonged contact with human skin, which is why it’s widely used in earphone silicone plugs, medical-grade silicone plugs, and food‑grade silicone utensils—largely due to its unique material properties that enable such broad applications. In contrast, silicone plugs emphasize environmental benefits, a soft and comfortable texture, and ease of use. They’re commonly found in electronic devices, everyday household items, and small-scale waterproof or dustproof appliances. Their raw materials are produced through a precipitation process, combining fine silica particles with white carbon black to form a highly refined silicone resin. The resulting molecular structure ensures a soft, flexible material that feels exceptionally comfortable during use. When comparing silicone and rubber, one might liken them to new technology versus traditional industry applications: rubber has long been well‑known and widely used, while silicone products have gained increasing popularity in recent years. Silicone offers greater versatility than rubber, particularly in terms of environmental performance and advanced features like customizable shapes, patterns, and colors. www.mingzhen2006.com


What are the application areas of silicone buttons for devices?

Properties and Applications of Silicone Rubber Silicone rubber is a type of elastomer. After vulcanization, it exhibits excellent resistance to heat, cold, ozone, atmospheric aging, and superior electrical insulation properties. However, silicone rubber has relatively low tensile strength and elongation at break, along with significant compression set. It is suitable for manufacturing components that operate under high-temperature, low-temperature, sunlight, atmospheric, or ozone‑exposed conditions, as well as electrical insulating parts. Dimensional Accuracy and Recommended Tolerances Since silicone rubber is an elastomer, its shrinkage behavior is influenced by numerous complex factors compared to plastics, making dimensional accuracy more challenging. Therefore, designers should carefully account for these considerations during the design phase, avoiding overly stringent tolerances in critical areas. If the nominal dimensions are excessively large and cannot meet the required precision, a solution involving locating pins paired with substrate deformation can be employed. For areas where dimensional accuracy is essential, sufficient allowance should be provided during design to facilitate mold modifications. Etched Text and Patterns Trademarks and text can be designed directly onto the silicone rubber substrate and molded into the finished part. The resulting patterns and text may appear either raised (convex) or recessed (concave). For ease of mold fabrication, convex designs are typically preferred. To simplify future changes to markings or model numbers, the marking area can be designed as an insert component. When product models change, only the insert within the mold cavity corresponding to the marking needs replacement, thus facilitating quick updates. In designing such components, allowances should be made for slight flash or edge burrs around the edges of the marking insert. For conductive rubber, an actuation travel of 0.8–1.5 mm is generally recommended. Venting grooves (or air vents) are incorporated to prevent adhesion between the button and the PCB during operation. For tactile switches, the actuation travel depends on the switch’s inherent stroke and anti‑misoperation features, as detailed later. If the substrate does not need to be bonded to the PCB, the venting groove can be omitted. Button design also involves tactile feel, which varies according to the specific curve profile. Based on experience, a favorable tactile response is achieved when the ratio (FP−FC)/FP falls within 40%–60%. Typical Button Structures and Applications Depending on the specific application and the product's requirements regarding lifespan, actuation force, tactile feedback, and other performance criteria, the following table outlines common button structures and their respective applications. The service life of silicone rubber buttons is closely tied to material selection and the geometry of inclined walls, and should be determined based on design needs. Reference lifetimes for silicone rubber buttons in various products: - Remote controls: approximately 500,000 cycles - Telephones: approximately 1 million cycles - Laptops: approximately 4–5 million cycles - Computer keyboards: approximately 5–10 million cycles - Medical monitoring devices: defined as over 500,000 cycles - Ultrasound equipment: typically rated at over 1 million cycles These figures provide general guidelines; actual lifetimes may vary depending on usage conditions and environmental factors.


The convenience brought by industrial silicone buttons

To address the aforementioned issues and technical shortcomings, a multi-station silicone button trimming machine has been developed through continuous improvements and redesigns, and a utility model patent has been filed. This utility model—a multi-functional silicone button trimming machine—comprises a base, a gantry frame, and four cutting cylinders arranged horizontally in a straight line, vertically mounted on the top of the gantry frame. The beneficial effects achieved by this utility model are as follows: its structural design is rational; by integrating four reinforcing platforms with four cutting blades on the gantry frame, the device can simultaneously perform edge-trimming operations on four silicone button products, significantly enhancing the efficiency of silicone product edge-trimming processes. As the market for silicone buttons continues to expand, improving processing efficiency has become increasingly important for manufacturers. Edge-trimming of silicone buttons is a critical step in their production process; however, traditional methods have failed to improve trimming efficiency, thereby negatively impacting overall production output. Various types of silicone gel exhibit different microporous structures depending on their manufacturing methods. Its chemical composition and physical structure give silicone unique characteristics that are difficult to replace with other similar materials, such as high adsorption capacity, excellent thermal stability, stable chemical properties, and superior mechanical strength. Based on pore size, silicone gels are classified into macroporous silica gel, mesoporous silica gel, Type B silica gel, and microporous silica gel. www.mingzhen2006.com


What are the molding techniques for rubber products?

Calendering: This method is suitable for producing simple sheet‑like or plate‑like products. It involves passing a compounded rubber compound through a calender machine to form thin rubber sheets. For certain rubber products—such as tires, adhesive tapes, and rubber hoses—textile fibers are coated with a thin layer of rubber; this coating process is typically carried out on a calendering machine as well. Before calendering, fiber materials must undergo drying and rubber impregnation. Drying reduces the moisture content of the fibers (to prevent bubbling caused by evaporation) and raises their temperature, ensuring high-quality calendering. Rubber impregnation, performed prior to coating, enhances the bonding between the fibers and the rubber compound. Extrusion Molding: This technique is used for more complex rubber products, such as tire treads, rubber tubes, and surface coatings for metal wires, which require extrusion molding for production. The plasticized rubber compound is loaded into the hopper of an extruder. Under the pressure of the screw, it is continuously shaped through various die openings. Prior to extrusion, the rubber compound is preheated to make it softer and easier to extrude, resulting in rubber products with smooth surfaces and precise dimensions. The rubber industry is one of the vital foundational sectors of the national economy. It not only supplies essential light‑industry rubber products for everyday use but also provides various rubber components and equipment for heavy industries and emerging sectors, including mining, transportation, construction, machinery, and electronics. Clearly, the rubber industry offers a wide variety of products and plays a significant role across numerous industrial fields. Compression Molding: Certain rubber products with complex shapes—such as diaphragms and sealing rings—can also be manufactured using compression molding. In this process, the rubber compound is placed into a male or female mold and then heated to achieve the desired shape. www.mingzhen2006.com


How do you print a pattern onto a translucent key?

Some laser marking machines, when used to create translucent keys, can also scorch the transparent plastic parts while removing the paint, leaving them opaque. However, a specialized device installed on Changzhou laser marking machines allows the machine to be configured for laser processing of translucent keys. This enables the laser to cleanly remove surface coatings without damaging the transparent plastic, thus achieving precise laser engraving of translucent keys. Conventional YAG laser marking machines generally cannot produce translucent keys. Translucent keys, also known as light‑transmitting buttons, are commonly used in electronic devices. In dark environments, they allow users to easily and accurately locate each button. A typical translucent key consists of a translucent key body, an electronic switch positioned beneath the key body, and a light‑emitting element mounted on one side below the key body. Beneath the key body is a light guide with a main body; the upper surface of this body extends toward the electronic switch, forming an extension. The outer surface of this extension serves as a first reflective inclined surface, while the lower surface acts as a second reflective inclined surface that also functions as a touch‑sensitive contact surface for the electronic switch. Additionally, there is an optical entry port connected to the extension and aligned with the light‑emitting element. When the light source emits light, it enters through the entry port, strikes the first reflective inclined surface, and is reflected into the main body. Inside the body, the light is further reflected by the second inclined surface and exits through the key body. This design ensures more uniform light emission from the key’s visible surface, enhancing its aesthetic appeal and helping users precisely identify the intended function. The patterns and text on these keys are created using laser marking technology. In our daily lives, many devices feature laser‑marked, translucent keys and buttons—such as mobile phone keys, car audio control buttons, computer keys, and various other electronic appliance switches. www.mingzhen2006.com


What are the basic parameters of silicone rubber products?

Silicone rubber has an extremely wide range of applications due to its non-toxic nature, lack of adhesion to other materials, and ability to withstand repeated steam sterilization. It is extensively used in the medical and food industries, including medical devices, drinking water equipment, sports gear, electronics, electrical appliances, lighting fixtures, audio equipment, toys, security surveillance systems, automobiles, and industrial machinery. Silicone rubber flexible joints are linear polymeric elastomers containing silicon-oxygen bonds, giving them exceptional thermal stability. They also exhibit excellent resistance to ozone aging, oxidative aging, photo‑aging, and weathering, along with superior electrical insulation, mildew resistance, and high gas permeability. Furthermore, they maintain consistent performance across a broad temperature range, from −70°C to +250°C. Thermal conductive silicone sheets are heat‑transfer materials synthesized through a special process, using silicone as the base material and incorporating various auxiliary components such as metal oxides. These sheets offer excellent thermal conductivity and high dielectric strength, and are commonly referred to in the industry as thermal conductive silicone pads, insulating thermal sheets, or soft heat‑dissipation pads. They possess five key characteristics: ease of application, high thermal conductivity, dimensional stability, electrical insulation, and sound absorption and vibration damping. In addition, silicone products manufacturers utilize silicone rubber as a coating or sealant for various vacuum tubes and electrical components, providing moisture resistance, dust protection, and shock absorption. www.mingzhen2006.com

Leave a Message Online

Professional service team response

Submit Message